Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Estimation of groundwater storage from seismic data using deep learning     

Timo Lähivaara  Alireza Malehmir  Antti Pasanen  Leo Kärkkäinen  Janne M.J. Huttunen  Jan S. Hesthaven 《Geophysical Prospecting》2019,67(8):2115-2126

Convolutional neural networks can provide a potential framework to characterize groundwater storage from seismic data. Estimation of key components, such as the amount of groundwater stored in an aquifer and delineate water table level, from active-source seismic data are performed in this study. The data to train, validate and test the neural networks are obtained by solving wave propagation in a coupled poroviscoelastic–elastic media. A discontinuous Galerkin method is applied to model wave propagation, whereas a deep convolutional neural network is used for the parameter estimation problem. In the numerical experiment, the primary unknowns estimated are the amount of stored groundwater and water table level, while the remaining parameters, assumed to be of less of interest, are marginalized in the convolutional neural network-based solution. Results, obtained through synthetic data, illustrate the potential of deep learning methods to extract additional aquifer information from seismic data, which otherwise would be impossible based on a set of reflection seismic sections or velocity tomograms.  相似文献   

Spinel assemblages in lunar meteorites Graves Nunataks 06157 and Dhofar 1528: Implications for impact melting and equilibration in the Moon's upper mantle     

Axel Wittmann  Randy L. Korotev  Bradley L. Jolliff  Paul K. Carpenter 《Meteoritics & planetary science》2019,54(2):379-394

Magnesium‐rich spinel assemblages occur in the two lunar vitric breccia meteorites—Dhofar (Dho) 1528 and Graves Nunataks (GRA) 06157. Dho 1528 contains up to ~0.7 mm cumulate Mg‐rich spinel crystals associated with Mg‐rich olivine, Mg‐ and Al‐rich pyroxene, plagioclase, and rare cordierite. Using thermodynamic calculations of these mineral assemblages, we constrain equilibration depths and discuss an origin of these lithologies in the upper mantle of the Moon. In contrast, small, 10 to 20 μm spinel phenocryst assemblages in glassy melt rock clasts in Dho 1528 and GRA 06157 formed from the impact melting of Mg‐rich rocks. Some of these spinel phenocrysts match compositional constraints for spinel associated with “pink spinel anorthosites” inferred from remote sensing data. However, such spinel phenocrysts in meteorites and Apollo samples are typically associated with significant amounts of olivine ± pyroxene that exceed the compositional constraints for pink spinel anorthosites. We conclude that the remotely sensed “pink spinel anorthosites” have not been observed in the collections of lunar rocks. Moreover, we discuss impact‐excavation scenarios for the spinel‐bearing assemblages in Dhofar 1528 and compare the bulk rock composition of Dho 1528 to strikingly similar compositions of Luna 20 samples that contain ejecta from the Crisium impact basin.  相似文献   

The Assessment of the Diffuse Pollution from Agricultural Territories in the Upper Volga Basin and the Development of Measures to Reduce It: Case Study of the Yakhroma River     

Kireycheva  L. V.  Lentyaeva  E. A.  Timoshkin  A. D.  Yashin  V. M. 《Water Resources》2020,47(5):709-720

Water Resources - The possible input of nutrients-pollutants into water bodies in the Upper Volga basin from agricultural lands is evaluated for the case of the Yakhroma R. with a basin area of...  相似文献   

Decadal link between longitudinal morphological changes in branching channels of Yangtze estuary and movement of the offshore depo-center     

Boyuan Zhu  Yao Yue  Alistair G.L. Borthwick  Wenjun Yu  Enhang Liang  Jinwu Tang  Yuanfang Chai  Yitian Li 《地球表面变化过程与地形》2020,45(11):2689-2705

In estuaries, the morphology of inland and offshore areas usually evolves synergistically. This study examines the decadal link between longitudinal changes in morphology of branching channels and movement of the offshore depo-center (where sediment deposition rate is maximum) of the Yangtze River estuary, under intense human interference. Integrated data analysis is provided on morphology, runoff discharge, and ebb partition ratio from 1950 to 2017. Channel-volume reductions and change rates between isobaths in branching channels reflect the impact of estuarine engineering projects. Ebb partition ratio and duration of discharge ≥ 60 000 m³ s^-1 act as proxies for the water excavating force in branching channels and runoff intensity. It is found that deposition occurs in the lower/upper sub-reaches (or further downstream/upstream channels) of the inland north/south branching channels, and the offshore depo-center moves southward or southeastward, as runoff intensity grows; the reverse occurs as runoff intensity declines. This is because the horizontal circumfluence in the Yangtze estuary rotates clockwise as ebb partition ratios of the north/south branching channels increase/decrease for increasing runoff, and conversely rotates anticlockwise for decreasing runoff. Land reclamation activities, the Deepwater Channel Project, and the Qingcaosha Reservoir have impacted greatly on longitudinal changes of morphology in the North Branch and the South Passage and on ebb partition ratio variations in the North/South Channel and the North/South Passage. Dam-induced runoff flattening has enhanced deposition in the upper/lower sub-reaches of the north/south branching channels and caused northward movement of the offshore depo-center, except in areas affected by estuarine engineering projects. Dam-induced longitudinal evolution of branching channel morphology and offshore depo-center movement will likely persist in the future, given the ongoing construction of large cascade dams in the upper Yangtze and the completion of major projects in the Yangtze estuary. © 2020 John Wiley & Sons, Ltd.  相似文献   

Intercomparison of measurements of bulk snow density and water equivalent of snow cover with snow core samplers: Instrumental bias and variability induced by observers     

J. Ignacio López-Moreno  Leena Leppänen  Bartłomiej Luks  Ladislav Holko  Ghislain Picard  Alba Sanmiguel-Vallelado  Esteban Alonso-González  David C. Finger  Ali N. Arslan  Katalin Gillemot  Aynur Sensoy  Arda Sorman  M. Cansaran Ertaş  Steven R. Fassnacht  Charles Fierz  Christoph Marty 《水文研究》2020,34(14):3120-3133

Manually collected snow data are often considered as ground truth for many applications such as climatological or hydrological studies. However, there are many sources of uncertainty that are not quantified in detail. For the determination of water equivalent of snow cover (SWE), different snow core samplers and scales are used, but they are all based on the same measurement principle. We conducted two field campaigns with 9 samplers commonly used in observational measurements and research in Europe and northern America to better quantify uncertainties when measuring depth, density and SWE with core samplers. During the first campaign, as a first approach to distinguish snow variability measured at the plot and at the point scale, repeated measurements were taken along two 20 m long snow pits. The results revealed a much higher variability of SWE at the plot scale (resulting from both natural variability and instrumental bias) compared to repeated measurements at the same spot (resulting mostly from error induced by observers or very small scale variability of snow depth). The exceptionally homogeneous snowpack found in the second campaign permitted to almost neglect the natural variability of the snowpack properties and focus on the separation between instrumental bias and error induced by observers. Reported uncertainties refer to a shallow, homogeneous tundra-taiga snowpack less than 1 m deep (loose, mostly recrystallised snow and no wind impact). Under such measurement conditions, the uncertainty in bulk snow density estimation is about 5% for an individual instrument and is close to 10% among different instruments. Results confirmed that instrumental bias exceeded both the natural variability and the error induced by observers, even in the case when observers were not familiar with a given snow core sampler.  相似文献   

Subsurface flow measurements using passive flux meters in variably-saturated cold-regions landscapes     

Élise G. Devoie  Ryan F. Connon  James R. Craig  William L. Quinton 《水文研究》2020,34(23):4541-4546

To date, passive flux meters have predominantly been applied in temperate environments for tracking the movement of contaminants in groundwater. This study applies these instruments to reduce uncertainty in (typically instantaneous) flux measurements made in a low-gradient, wetland dominated, discontinuous permafrost environment. This method supports improved estimation of unsaturated and over-winter subsurface flows which are very difficult to quantify using hydraulic gradient-based approaches. Improved subsurface flow estimates can play a key role in understanding the water budget of this landscape.  相似文献   

不同类型洞体应变仪的观测差异性分析          下载免费PDF全文

孙伶俐  蒋玲霞  吕琳  张辉  邓建刚 《地震工程学报》2020,42(1):129-135

运用SPSS中聚类及PCA方法对湖北省7个台站三类基线(石英管、铟钢棒、铟钢管)洞体应变观测记录进行相关统计分析,归纳总结其潮汐参数变化特征差异,并针对观测中自然环境因素影响进行定量分析。结果显示:(1)三类基线中,铟钢棒类M2波潮汐因子、中误差及M1波相对噪声水平较低,铟钢棒管年均漂移量最小;(2)自然环境因素(气压、降水、雷雨、温度)对湖北地区洞体应变观测影响较为显著,等量气压影响下应变量最小的为铟钢管型,等量温度影响下应变量最小的为铟钢棒型。  相似文献   

微量元素锰对底栖甲藻热带库里亚藻(Coolia tropicalis)生长及叶绿素荧光特性的影响     

刘莎莎  陈亨  黄凯旋  吕颂辉  张亮  谢学东 《热带海洋学报》2020,39(3):76-85

以热带库里亚藻(Coolia tropicalis)为研究对象, 在不同锰浓度(0、1、5、10、50μmol·L ^-1)的人工海水培养15d, 利用叶绿素荧光动力学技术研究了其生长和光合作用对不同锰环境的响应。结果表明: 1)比生长速率(μ)和最大相对电子传递速率(rETR_max)与锰浓度均呈指数关系且对锰胁迫具有相同程度的响应; 2)锰浓度至少大于1μmol·L ^-1才能维持热带库里亚藻正常的光合作用活性, 当锰浓度低于该浓度时, 光合作用活性(F_v/F_m)在6d后开始下降, 而单位反应中心吸收光能(ABS/RC)和热能耗散(DI₀/RC)升高; 两个反应中心之间的电子传递(φ_E0)及生长并未受影响, 表明此阶段锰缺乏只影响活性光反应中心数量并提高热耗散途径; 当锰缺乏延长至15d时, 胁迫作用显现(F₀上升)并且电子传递(φ_E0)和生长受到抑制, 这阶段锰缺乏使光反应中心关闭且电子传递受阻; 3)锰缺乏的修复损伤比(r/k)并未降低, 表明锰缺乏并未影响热带库里亚藻的光保护能力。  相似文献   

亚热带地区发育于不同母岩风化壳上的红壤磁学特征对比及其环境意义   总被引：1，自引：0，他引：1       下载免费PDF全文

郑兴芬  吕镔  陈梓炫  马兴悦  赵国永 《地球物理学报》2019,62(9):3509-3523

本研究对发育于亚热带地区花岗岩和变质岩风化壳之上的两个红壤剖面进行了系统的环境磁学测量及色度分析，探讨在同一地区不同母质上发育的红壤磁性差异的原因及其环境意义.研究区的两个剖面分别位于福建省南平市高铁北站和纺织厂附近，相距约15 km，气候条件基本相同.研究结果表明：（1）较强磁性的花岗岩母质层上发育的南平北站红壤（NPN），在发育过程因母质层中多畴（MD）颗粒磁赤铁矿化的磁铁矿溶解，剖面上部的淋溶层和淀积层虽以较细的稳定单畴（SSD）颗粒和少量的假单畴（PSD）颗粒磁铁矿为主，但剖面磁性自下而上减弱.相较而言，南纺红壤（NF）剖面发育在磁性较弱的变质砂岩上，其过渡层和母质层以赤铁矿为主，因成壤过程中生成较细的超顺磁（SP）磁铁矿使得土壤淋溶层和淀积层磁性增强；说明母质不同是亚热带地区红壤磁性差异的主要原因.（2） NPN和NF两个剖面的气候条件基本相同，磁性差异比色度指标差异更为显著.亚热带地区因剖面受母质影响显著，整体磁性特征不能反映气候；黄度和红度的比值（b^*/a^*）远小于磁性的差异，说明针铁矿和赤铁矿的比值更能反映研究区的平均气候状况，即反映次生磁性矿物含量的参数为更适合的气候指标.  相似文献